Not sure what to think as I understand that all pyrex dish's are heat proof,and IF you break or smash them,advice that you don't put them in the glass recycling box as they don't melt as they are made of hardened glass.
This goes back again that you should never throw warm or hot water over a frozen windscreen,as it may crack the windscreen.
I have never heard of any windscreen being broken by throwing warm or hot water over a frozen windscreen.
My thoughts is that you NEVER throw warm water over the windscreen,this is to safeguard any one walking by. Eventually the water will freeze again,Which could mean some one(it could be a relative or friend) visiting, ending up falling down and possible breaking an arm or even something worse. Think of your fellow citizens