DH insists that mushrooms are peeled although I have told him that they are grown in very "clean" conditions and the heat required to cook them would kill any nasties [I'm a microbiologist]...
A quick rinse won't get rid of pesticides, but might remove the worst of them, ditto bacteria. I rarely rinse as I mostly cook my fruit and veg.
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). I peel veg like carrots and parsnips and often peel mushrooms although my husband just washes those. Must admit I've thought about washing the outside of a melon although never done it but how on earth do you wash the outside of a pineapple?! 
