One of the dangers in getting too involved is that, whichever way things go in the end, you may find yourself in a difficult situation. If they patch things up, you will have been the recipient of negative remarks that might make it hard for either party to relax in your company. If they part, your ex-DIL might be difficult about you seeing the GC for instance, as she will resent your involvement.
So much better to stand back, to say how sorry you are that things are not working out, but to avoid direct involvement or advice except, as Jane says guiding them towards professional help.
Whatever the outcome it is in your and the GCs' interests for you to stay on good terms with all parties, wherever you judge the rights and wrongs to be.