Depends on reason for 'choosing' the school ...if it has some special significance eg private, independent, grammar ...then the uniform could mean a target ...for a variety of reasons including the technology that may be carried.
On the other hand if it is the local secondary school ...then children from the "not especially nice part of town" could/would be going there too.
I would suggest that you initially contact the school and ask if they are aware of any issues with this long walk ...if there have been issues in the past then that will help you plan ...but if not, that could also guide you ...perhaps the other mothers are concerned more about suddenly allowing their sons that degree of independence?
All of you would have known about this walk when you opted for this school ...so I wonder about the sudden concern ...is this one mother, stirring you all up?
Have you discussed this with your son?
Yes bad weather, dark winter nights may alter your arrangements ...but this is the middle of August ...these decisions were made months ago ...so think carefully about why this is surfacing now.
Lack of public toilets in towns.