If it is Aluminium, it would be a good idea to apply a primer intended for Aluminium after rubbing down the surface.
For steel you will need a different primer, such as red oxide.
If you spray, try to find a windless day, or set up a windbreak. Brushing Hammerite, tends to dry quickly, so work quickly and don't overload the brush, it won't spread too far before starting to dry out. Two thin coats are better than one tick one.
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