The best and only way to help is to listen, nod sympathetically and let her know you love her and will always be there for her. Never give advise, or actually do anything.
I had so many problems with first half of my second marriage due to my OH's 'baggage' ....it was all so complicated...the situation itself i.e. the 'facts' then there was his attitude to it, my attitude, the affects upon the children...etc etc. All my Mum ever did was listen and smile......it was the best thing to do, anything else just opens up a hundred and one more 'cans of worms' believe me....if its complicated for those within the relationships to gets to grips with it all, its impossible for others and its actually dangerous for others to get involved....it can and will blow up in everyone's face.