Having read through your post I will offer my advice:
It seems to be that maybe your relationship with your daughter was possibly not as close as you thought, just some remarks you make about her mental health issues which do not seem to have stopped her aiming for a very lucrative career. You also say she 'blames' her father for these issues but is not in contact with him.
You also say she has been spiteful and controlling, but yet she doesn't seem to want to contact you. Maybe she's given up on trying to control you? I don't know. You then match this by saying she can be generous and loving?
I'm sorry to hear about the death of your brother- you mention that she came to the funeral but she was not supportive enough. I have to ask how supportive did you expect her to be?
You then also express that you hope she may see the error of her ways? This sounds a little petty to me, as if everything is her fault and this fracture is nothing to do with any thing you have done.
My advice is to:
Be proud of your daughter and what she has achieved
Stop having unrealistic expectations of how she should behave towards you
Stop having unrealistic expectations of yourself- that you have to be some sort of victim here.
You have raised a successful adult child and that is to your credit, but maybe now it is time to be a grown-up youself and let her be who she is.
I also notice your husband and daughter seem to be in contact with her- so maybe an honest conversation with your family members is in order here.
Just my advice.
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