It’s commendable that you want to include this wee boy in your family and I agree with others who say that the dynamics with the ex seem to be the motivating factor here.
That said, he’s only 5 and has had a lot of change in his wee life, a new step dad, a new sibling on the way, a new home and living a large part of his life through the restrictions of a pandemic.
Try and be patient? They seem to have a lot going on settling in as their own family whilst negotiating the pressures of the ex and his extended family.
The ADHD thing may be a genuine concern, but teachers etc will pick up on that when he starts school which means that there will be support for the lad, which the ex won’t be able to argue against without welfare concerns being raised against him. That said my two would never in a month of Sundays sat still to chat to anyone on a video call at that age - never mind after over a year of on and off confinement due to lockdown.
In your shoes I wouldn’t apply any pressure, but follow their lead on this one. Assuming your son and his GF are in this for the long haul you will have many years ahead of you to look forward to with both the children.