If you monitor the supermarket sites all day long, you find that a few slots can come up randomly at any time of day (at least that is my experience with Tesco and Morrisons).
You can't predict when they will come up, unlike the slots that generally come up at midnight.
I guess that this website alerts people when these random slots appear, but that you will have to be quick off the mark ....
Why are they doing it if they don't charge? Some people just do things because they can!
Another Tory MP crosses the floor