I think the issue here is that her husband was addressed by name, not the spam emails themselves.
I know that I occasionally get emails intended for the Bodach, as he only very rarely used the internet, so if something asked for an email address, he gave mine. These emails usually bear no resemblance to things where he might have given my address ( car insurance and golf supplies are two I can think of).
As her husband has his own email account, I agree it would be a bit daft to use hers if he was up to no good! I also suggest asking him.